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|
long-chain_fatty_acyl-[mycocerosate_synthase] + (S)-methylmalonyl-CoA + NADPH + H+ <=> a_mycocerosyl-[mycocerosic_acid_synthase] + CoA + CO2 + NADP+ + H2O
|
2.3.1.111
mycocerosate synthase
|
–
|
| |
MetaCyc:
RXN-18052
|
|
|
|
mycoside_B + dTDP-L-rhamnose <=> [alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]_dimycocerosyl_phenol-phthiocerol + dTDP + H+
|
2.4.1.M4
|
–
|
| |
MetaCyc:
RXN-17278
|
|
|
|
a_phenolphthiocerol + a_mycocerosyl-[mycocerosic_acid_synthase] <=> a_dimycocerosyl_phenolphthiocerol + holo-[mycocerosate_synthase]
|
2.3.1.282
phenolphthiocerol/phthiocerol/phthiodiolone dimycocerosyl transferase
|
–
|
| |
BRENDA:
BR52686
MetaCyc:
RXN-17258
|
|
|
|
fatty_acid + ATP + H+ <=> a_long-chain_fatty-acyl_adenylate_ester + diphosphate
|
6.2.1.59
long-chain fatty acid adenylase/transferase FadD26
|
–
|
| |
BRENDA:
BR52955
MetaCyc:
RXN-17251
|
|
|
|
S-adenosyl-L-methionine + [2-O-methyl-alpha-L-fucopyranosyl-(1rarr3)-alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]_dimycocerosyl_phenol-phthiocerol <=> [2,4-di-O-methyl-alpha-L-fucopyranosyl-(1rarr3)-alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]_dimycocerosyl_phenol-phthiocerol + S-adenosyl-L-homocysteine + H+
|
2.1.1.M15
|
–
|
| |
MetaCyc:
RXN-17281
|
|
|
|
a_long-chain_fatty-acyl_adenylate_ester + holo-[mycocerosate_synthase] <=> long-chain_fatty_acyl-[mycocerosate_synthase] + AMP + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18532
|
|
|
|
S-adenosyl-L-methionine + [2,4-di-O-methyl-alpha-L-fucopyranosyl-(1rarr3)-alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]_dimycocerosyl_phenol-phthiocerol <=> PGL-tb + S-adenosyl-L-homocysteine + H+
|
2.1.1.M16
|
–
|
| |
MetaCyc:
RXN-17282
|
|
|
|
a_dimycocerosyl_phenolphthiocerol + dTDP-L-rhamnose <=> (alpha-L-rhamnopyranosyl)_dimycocerosyl_phenol-phthiocerol + dTDP + H+
|
2.4.1.M3
|
–
|
| |
MetaCyc:
RXN-17249
|
|
|
|
[alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]_dimycocerosyl_phenol-phthiocerol + GDP-L-fucose <=> [alpha-L-fucopyranosyl-(1rarr3)-alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]_dimycocerosyl_phenol-phthiocerol + GDP + H+
|
2.4.1.M5
|
–
|
| |
MetaCyc:
RXN-17279
|
|
|
|
S-adenosyl-L-methionine + [alpha-L-fucopyranosyl-(1rarr3)-alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]_dimycocerosyl_phenol-phthiocerol <=> [2-O-methyl-alpha-L-fucopyranosyl-(1rarr3)-alpha-L-rhamnopyranosyl-(1rarr3)-2-O-methyl-alpha-L-rhamnopyranosyl]_dimycocerosyl_phenol-phthiocerol + S-adenosyl-L-homocysteine + H+
|
2.1.1.M14
|
–
|
| |
MetaCyc:
RXN-17280
|
|
|
|
S-adenosyl-L-methionine + (alpha-L-rhamnopyranosyl)_dimycocerosyl_phenol-phthiocerol <=> mycoside_B + S-adenosyl-L-homocysteine + H+
|
2.1.1.M13
|
–
|
| |
MetaCyc:
RXN-17277
|
|
